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1-十九烷醇

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1-十九烷醇
Structural model of 1-nonadecanol
IUPAC名
nonadecan-1-ol
別名 1-十九醇
正十九醇
識別
CAS號 1454-84-8  checkY
PubChem 80281
ChemSpider 72522
SMILES
 
  • CCCCCCCCCCCCCCCCCCCO
性質
化學式 C19H40O
摩爾質量 284.52 g·mol−1
熔點 59—61 °C(332—334 K)[1]
62—63 °C(335—336 K)[2]
沸點 204—217 °C(477—490 K)(3 torr)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

1-十九烷醇是一種有機化合物,化學式為C19H40O,可由十九酸的還原反應製得。[3]它和三苯基膦催化下反應[4],或和四溴化碳、三苯基膦在二氯甲烷中反應[5],可以得到1-溴十九烷。它和對甲苯磺酰氯反應,生成相應的[6]

參考文獻

[編輯]
  1. ^ 1.0 1.1 James Cason, Helen J. Wolfhagen, Winifred Tarpey, Raylene E. Adams. BRANCHED-CHAIN FATTY ACIDS. X. SYNTHESIS OF ACIDS WITH BRANCHING METHYL GROUPS NEAR THE CARBOXYL. The Journal of Organic Chemistry. 1949-01, 14 (1): 147–154 [2021-03-17]. ISSN 0022-3263. doi:10.1021/jo01153a021 (英語). 
  2. ^ Scholl, A. W.; Morrison, J. G. Preparation and properties of n-nonadecyl and n-eicosyl formates. West Va. Univ. Bull., Proc. West Va. Acad. Sci., 1955. V1954. 26: 35-37. CAN50: 44260.
  3. ^ Juma'a R. Al Dulayymi, Mark S. Baird, Evan Roberts. The synthesis of a single enantiomer of a major α-mycolic acid of M. tuberculosis. Tetrahedron. 2005-12, 61 (50): 11939–11951 [2021-03-17]. doi:10.1016/j.tet.2005.09.056. (原始內容存檔於2018-07-02) (英語). 
  4. ^ Oldřich Kocián, Karel Stránský, Jiří Závada. Unsaturated analogues of 1-triacontanol. Collection of Czechoslovak Chemical Communications. 1982, 47 (5): 1346–1355 [2021-03-17]. ISSN 0010-0765. doi:10.1135/cccc19821346. (原始內容存檔於2018-06-05) (英語). 
  5. ^ Yasuhisa Yamamura, Yuri Nakazawa, Shoichi Kutsumizu, Kazuya Saito. Molecular packing in two bicontinuous Ia 3̄ d gyroid phases of calamitic cubic mesogens BABH( n ): roles in structural stability and reentrant behavior. Physical Chemistry Chemical Physics. 2019, 21 (42): 23705–23712 [2021-03-17]. ISSN 1463-9076. doi:10.1039/C9CP04424H (英語). 
  6. ^ Kaoru Marukawa, Hirosato Takikawa, Kenji Mori. Synthesis of the Enantiomers of Some Methyl-branched Cuticular Hydrocarbons of the Ant, Diacamma sp.. Bioscience, Biotechnology, and Biochemistry. 2001-01, 65 (2): 305–314 [2021-03-17]. ISSN 0916-8451. doi:10.1271/bbb.65.305. (原始內容存檔於2022-01-21) (英語).